Anion Exchange Studies of Beryllium (II), Cerium (IV), Thorium (IV) and Uranium(VI) Carbonate Complex Ions
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چکیده
منابع مشابه
Selective and Efficient Ligandless Water-in-Oil Emulsion Liquid Membrane Transport of Thorium(IV) Ions
The present paper concerns on the selective and very efficient transport of thorium(IV) ions from aqueous solutions through an emulsion liquid membranes composed by paraffin and a surfactant, without carrier requirement. The influence of pH of the external aqueous phase, the surfactant concentration in the membrane phase, the type, and concentration of th...
متن کاملAqueous complexation of thorium(IV), uranium(IV), neptunium(IV), plutonium(III/IV), and cerium(III/IV) with DTPA.
Aqueous complexation of Th(IV), U(IV), Np(IV), Pu(III/IV), and Ce(III/IV) with DTPA was studied by potentiometry, absorption spectrophotometry, and cyclic voltammetry at 1 M ionic strength and 25 °C. The stability constants for the 1:1 complex of each trivalent and tetravalent metal were calculated. From the potentiometric data, we report stability constant values for Ce(III)DTPA, Ce(III)HDTPA,...
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Phosphoryl containing ligand tri-n-octylphosphine oxide (TOPO) in dichloromethane has been used as an extracting agent for tetravalent thorium and trivalent europium ions from their 1 M sodium nitrates. The equilibrium data reveal that both ions are extracted as the complexes at 1:3 metal/ligand ratio. The values of conditional extraction equilibrium constant (Kex) show the superior extract...
متن کاملselective and efficient ligandless water-in-oil emulsion liquid membrane transport of thorium(iv) ions
the present paper concerns on the selective and very efficient transport of thorium(iv) ions from aqueous solutions through an emulsion liquid membranes composed by paraffin and a surfactant, without carrier requirement. the influence of ph of the external aqueous phase, the surfactant concentration in the membrane phase, the type, and concentration of the acid used in the receiving phase, the ...
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A mathematical model of sorption of Zirconium and Hafnium cations mixture and elution of these ions from a cation exchange resin bed is developed. Sulfuric acid is selected as the eluent for selective separation of Zr and Hf in a packed bed of Dowex cation exchange resin. The column model is a dispersed plug flow model,and assumed to consist of randomly packed synthetic and spherical resin ...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1959
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.32.876